發表論文
1. A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen vs. Sulfur-Gold Interactions. Crouthers, D. J.; Ding, S.; Denny, J. A.; Bethel, R. D.; Hsieh, C.-H.; Hall, M. B.; Darensbourg, M. Y., Angew. Chemie, Int. Ed.,2015,54,Accepted manuscript.
2. Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties. Bethel, R. D.; Crouthers, D. J.; Hsieh, C.-H.; Denny, J. A.; Hall, M. B.; Darensbourg, M. Y., Inorg. Chem.2015,54,3523-3535.
2. Metallodithiolates as Ligands to Dinitrosyl Iron Complexes: Toward the Understanding of Structures, Equilibria, and Spin Coupling. Pinder, T. A.; Montalvo, S. K.; Hsieh, C.-H.; Lunsford, A. M.; Bethel, R. D.; Pierce, B. S.; Darensbourg, M. Y., Inorg. Chem.,2014,53.9095—9105.
4. Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes. Pulukkody, R.; Kyran, S. J.; Drummond, M. J.; Hsieh, C.-H.; Darensbourg, D. J.; Darensbourg, M. Y., Chem.Sci.,2014,5,3795—3802.
5. Redox active iron nitrosyl units in proton reduction electrocatalysis. Hsieh, C.-H.; Ding, S.; Erdem, Ö. F.; Crouthers, D. J.; Lubitz, W.; Popescu, C. V.; Reibenspies, J. H.; Hall, M. B.; Darensbourg, M. Y., Nature Communications,2014,5,Article number 3684.
6. A Dinitrosyl Iron Complex as a Platform for Metal-Bound Imidazole to N-Heterocyclic Carbene Conversion.Randara Pulukkody, Samuel J. Kyran , Ryan D. Bethel , Chung-Hung Hsieh , Michael B. Hall , Donald J. Darensbourg, Marcetta Y. Darensbourg, Chem. Comm. 2013, 49, 9326-9328.
7. Versatile N2S2 Nickel-dithiolates as Mono- and Bridging Bidentate, S-donor Ligands to Gold(I). Pinder T. A.; Montalvo, S. K.; Lunsford, A. M.; Hsieh,C.-H.; Reibenspies,J. H.; Darensbourg, M. Y.*, Dalton Trans., 2013, 43, 138-144.
8. Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/ Thiolate Dinitrosyl Iron Complex (DNIC). Randara Pulukkody, Samuel J. Kyran, Ryan D. Bethel, Chung-Hung Hsieh, Michael B. Hall, Donald J. Darensbourg, Marcetta Y. Darensbourg, J. Am. Chem. Soc., 2013, 135, 8423-8430.
9. Ambidentate Thiocyanate and Cyanate Ligands in Dinitrosyl Iron Complexes. Chung-Hung Hsieh, Scott M. Brothers, Joseph H. Reibenspies, Michael B. Hall, Codrina V. Popescu, Marcetta Y. Darensbourg, Inorg. Chem. 2013, 52, 2119-2124.
10. Bridging-Hydride Influence on the Electronic Structure of an [FeFe]-Hydrogenase Active-Site Model Complex Revealed by XAES-DFT. N. Leidel, C-H Hsieh, P. Chernev, K. G. V. Sigfridsson, M. Y. Darensbourg, M. Haumann, Dalton Trans., 2013, 42, 7539-7554.
11. Hyperfine interactions and electron distribution in Fe(II)Fe(I) and Fe (I)Fe (I) models for the active site of the [FeFe] hydrogenases: Mossbauer spectroscopy studies of low-spin Fe(I). Sebastian A. Stoian, Chung-Hung Hsieh, Michael L. Singleton, Andrea F. Casuras, Marcetta Y. Darensbourg, Kelsey McNeely, Kurt Sweely, Codrina V. Popescu, J. Bio. Inorg. Chem., 2013, 18, 609-622.
12. Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase. Hsieh, C.-H.; Erdem, Ö. F.; Harman, S. D.; Singleton, M. L.; Reijerse, E.; Lubitz, W.; Popescu, C. V.; Reibenspies, J. H.; Brothers, S. M.; Hall, M. B.; Darensbourg, M. Y., J. Am. Chem. Soc. 2012,134, 13089–13102.
13. Dinitrosyl Iron Adducts of (N2S2)M(NO) Complexes (M = Fe, Co) as Metallodithiolate Ligands. Chung-Hung Hsieh, Rachel B. Chupik, Tiffany A. Pinder, Marcetta Y. Darensbourg, Polyhydron, 2013, 58, 151-155.
14. Towards Understanding the Electronic Response of the Fe(NO)2 Unit to “Spectator” Ligands in Dinitrosyl Iron Complexes. Brothers, S. M.; Hess, J. L.; Hsieh, C.-H.; Darensbourg, M. Y.*; Hall, M. B.*, Structure and Bonding, 2012, submitted.
15. Self-Assembly of Dinitrosyl Iron Units into Imidazolate-Edge-Bridged Molecular Squares: Characterization Including Mossbauer Spectroscopy. J. L Hess, C.-H. Hsieh, S. M. Brothers, M. B. Hall, M. Y. Darensbourg, J. Am. Chem. Soc. 2011, 133, 20426–20434.
16. N-Heterocyclic carbene ligands as mimics of histidines for the stabilization of di- and tri-nitrosyl iron complexes. Jennifer L. Hess, Chung-Hung Hsieh, Joseph H. Reibenspies, M. Y. Darensbourg, Inorg. Chem. 2011, 50, 8541-8552.
17. cis-Dithiolatonickel as Metalloligand to Dinitrosyl Iron Units: the Di-Metallic Structure of Ni(μ-SR)[Fe(NO)2] and an Unexpected, Abbreviated Metalloadamantyl Cluster, Ni2(μ-SR)4[Fe(NO)2]3. Chung-Hung Hsieh, Rachel B. Chupik, Scott M. Brothers, Michael B. Hall, Marcetta Y. Darensbourg, Dalton Trans. 2011, 40, 6047-6053.
18. A {Fe(NO)3}10 Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO)2}9/10 Products of Its NO Release. Chung-Hung Hsieh, Marcetta Y. Darensbourg, J. Am. Chem. Soc.,2010,132, 14118–14125.
19. Nitric Oxide Physiological Responses and Delivery Mechanisms Probed by Water-soluble Roussin’s Red Ester and {Fe(NO)2}10 DNIC. Chen, Y.-J.; Ku, W.-C.; Feng, L.-T.; Tsai, M.-L.; Hsieh, C.-H.; Hsu, W.-H.; Liaw, W.-F.*; Hung, C.-H.*; Chen, Y.-J.*, J. Am. Chem. Soc. 2008, 130, 10929-10938.
20. Dinitrosyl Iron Complexes (DNICs) Containing S/N/O Ligation: Transformation of Roussin’s Red Ester into the Neutral {Fe(NO)} DNICs. Tsai, M.-L.; Hsieh, C.-H.; Liaw, W.-F.*, Inorg. Chem., 2007; 46, 5110-5117
21. New members of a Class of Iron-Thiolate-Nitrosyl Compounds: Trinuclear Iron-Thiolate-Nitrosyl Complexes Containing FeS Core. Hsu, I.-J.; Hsieh C.-H.; Ke S.-C.*; Chiang K.-A.; Lee J.-M.; Chen J.-M.; Jang L.-Y.; Lee G.-H.; Wang Y.*; Liaw, W.-F.*, J. Am. Chem. Soc. 2007, 129, 1151-1159
22. Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]– Leading to Reversible Formation of [S5Fe(μ-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe-2S] Ferredoxin. Tsai, M.-L.; Chen, C.-C.; Hsu, I.-J.; Ke, S.-C.; Hsieh, C.-H.; Chiang, K.-A.; Lee, G.-H.; Wang, Y.; Chen, J.-M.; Lee, J.-F.; Liaw, W.-F. *, Inorg. Chem., 2004; 43, 5159-5167
23. Oxygen Binding to Sulfur in Nitrosylated Iron-Thiolate Complexes: Relevance to the Fe-Containing Nitrile Hydratases. Lee,C.-M.; Hsieh, C.-H.; Dutta, A.; Lee, G.-H.; Liaw, W.-F.*, J. Am. Chem. Soc. 2003, 125, 11492-11493
24. Nickel Complex of o-amidochalcogenophenolate (2-) /o-iminochalcogenobenzosemiquinonate (1-) π-radical: Synthesis, Structures, Electron Spin Resonance and X-ray Absorption Spectroscopic Evidence. Hsieh, C.-H.; Hsu, I-J.; Lee, C.-M.; Ke S.-C.; Wang T.-Y.; Lee G.-Hs.; Wang, Y.; Chen, J.-M.; Lee, J.-F.; Liaw, W.-F.*, Inorg. Chem. 2003, 42, 3925-3933.
25. Bioinorganic and Coordinated Chemistry. Chen; C.-H.; Lee, C.-M.; Hsieh, C.-H.; Liaw, W.-F.*, Chemistry (The Chinese Chem. Soc., Taipei) 2003, 61, 79-86.
26. S-S Bond-activation of diorganyl disulfide by anionic [Mn(CO)5]−: crystal structures of [MnII(SC5H4NO)3]− and [(CO)3Mn(μ-SR)3Co(μ-SR)3Mn(CO)3]− (R=C6H4NHCOPh). Liaw, W.-F.*; Hsieh, C.-H.; Lee G.-H., Inorg. Chim. Acta. 2002, 332, 153-159
27. Five-Coordinate Sixteen-Elecron Manganese(I) Complex [Mn(CO)3(S, S-C6H4)]– Stabilized by S, S π-Donation of Chelating [S, S-C6H4)]2- Ligand. Lee,C.-M.; Lin, G.-Y.; Hsieh, C.-H.; Hu, C.-H.; Lee G.-H.; Peng S.-M.; Liaw, W.-F.*, J. Chem. Soc., Dalton Trans. 1999, 2393-2398
演講 (2012- )
The 245th American Chemical Society National Meeting & Exposition, 2013
Division of Inorganic Chemistry:
Ambidentate thiocyanate ligand in dinitrosyl iron complexes
The 244th American Chemical Society National Meeting & Exposition, 2012
Division of Inorganic Chemistry:
Base-Promoted Tautomerization of Imidazoles to N-Heterocyclic Carbenes (NHCs): via a Dinitrosyl Iron scaffold